Identification and genesis of the Late Jurassic volcanic rocks in Longquan area, southern Zhejiang Province
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摘要:
浙江晚中生代大规模火山活动始于晚侏罗世还是早白垩世，长期以来存在争议。本文对浙南龙泉地区火山岩进行了锆石U-Pb定年，获得一批高精度的年代学数据，其SHRIMP锆石U-Pb和LA-ICP-MS锆石U-Pb年龄集中于163~145 Ma，确认浙江晚中生代火山活动始于晚侏罗世。地球化学特征和Sr-Nd同位素特征表明这套晚侏罗世火山岩具有高硅、高钾、低磷、贫铁镁的特征，属于过铝质高钾钙碱性岩石系列。由于晚中生代太平洋板块的俯冲作用，导致了下部地壳物质（基底变质岩）广泛熔融，形成了本区晚侏罗世火山岩浆活动。为了便于表达、对比，笔者建议新建“晚侏罗世黄茅尖群”地层单位。
Abstract:There has been controversy for a long time that the large-scale volcanic activity of Late Mesozioc in Zhejiang Province began with Late Jurassic or Early Cretaceous? Through zircon U-Pb geochronologic study of volcanic rocks in Longquan area of southern Zhejiang Province, a batch of high precision chronologic data were obtained. These zircon U-Pb ages are between 163 Ma to 145 Ma which were confirmed by SHRIMP and LA-ICP-MS. These data indicate that large-scale volcanic avtivity in Zhejiang Province began with Late Jurassic. According to geochemical characteristics and Sr-Nd isotope analysis, these Late Jurassic volcanic rocks belong to peraluminous and high potassium Ca-alkaline series characterized by high SiO2, K2O but low P2O5, FeOT and MgO. Due to the subduction of the Pacific plate in Late Mesozoic, the lower crust material (basement metamorphic rocks) was extensively melted and the late Jurassic volcanic-magmatic rocks in this area were formed. In addition, the authors propose defining a new rock-stratigraphic unit named" the Late Jurassic Huangmaojian Group"so as to better express and contrast.
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图 1 研究区地质简图
1—第一旋回第一亚旋回火山岩；2—第一旋回第二亚旋回火山岩；3—第一旋回第三亚旋回火山岩；4—第二旋回火山岩；5—第三旋回火山岩；6—早侏罗世枫坪组；7—潜火山岩；8—前泥盆纪变质岩、侵入岩；9—溢流相流纹岩/石泡流纹岩；10—火山颈相集块角砾熔岩；11—空落相流纹质含角砾晶玻屑凝灰岩；12—流纹质玻屑凝灰岩；13—碎屑流相流纹质晶屑熔结凝灰岩；14—喷发沉积相凝灰质砂岩；15—角度不整合界线；16—断层界线；17—同位素采样位置及编号；18—剖面位置
Figure 1. Geological map of the study area
1-Volcanic rocks of Ⅰ1 cycle; 2- Volcanic rocks of Ⅰ2 cycle; 3- Volcanic rocks of Ⅰ3 cycle; 4- Volcanic rocks of Ⅱ cycle; 5- Volcanic rocks of Ⅲ cycle; 6-Fengping Formation of early Jurassic; 7-Subvolcanic rock; 8-Pre-Devonian metamorphic rock and intrusive rock; 9-Flooding rhyolite/ lithophysa rhyolite; 10-Volcanic neck facies breccia and conglomerate lava; 11-Rhyolitic breccias crystal glass tuff formed by Empty stacked phase; 12-Rhyolitic glass tuff formed by Empty stacked phase; 13-Rhyolitic crystal welded tuff formed from pyroclastic flow accumulation; 14- Tuffaceous sandstone formed from eruption-sedimentary; 15-Angular unconformity; 16-Fault; 17-Isotope sampling position; 18-Profile position
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图 2 研究区火山岩柱状图简图
1—流纹质晶玻屑熔结凝灰岩；2—流纹质含角砾晶屑熔结凝灰岩；3—流纹质角砾熔结凝灰岩；4—流纹质晶玻屑凝灰岩；5—流纹质凝灰熔岩；6—（石泡）流纹岩；7—流纹质凝灰岩；8—凝灰质砂岩
Figure 2. Columnar section of the volcanic rocks in the study area
1-Rhyolitic crystal-vitric welded tuff; 2-Rhyolitic breccias crystal glass welded tuff; 3-Rhyolitic breccia welded tuff; 4-Rhyotaxitic crystal-vitric tuff; 5-rhyolitic tufflava; 6-Lithophysa rhyolite; 7- Rhyolitic tuff; 8-Tuffaceous sandstone
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图 3 流纹质熔结凝灰岩（a，b）、流纹岩（c）及石泡流纹岩（d）显微照片（正交偏光）
qz—石英；kfs—钾长石
Figure 3. Microphotograph of rhyolitic welded tuff (a, b), rhyolite (c) and lithophysa rhyolite (d) (crossed nicols)
qz-Quartz; kfs-K-feldspar
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图 5 研究区晚侏罗世火山岩锆石U-Pb年龄谐和图
Figure 5. Zircon U-Pb concordia diagrams of the volcanic rocks in the study area
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图 6 研究区火山岩判别图解
a—火山岩TAS图解（Le Maitre，1989；Pc—苦橄玄武岩；B—玄武岩；O1—玄武安山岩；O2—安山岩；O3—英安岩；R—流纹岩；S1—粗面玄武岩；S2—玄武质粗面安山岩；S3-粗面安山岩；T—粗面岩、粗面英安岩；F—副长石岩；U1—碱玄岩、碧玄岩；U2—响岩质碱玄岩；U3-碱玄质响岩；Ph—响岩；Ir—Irvine分界线，上方为碱性，下方为亚碱性）；b—A/CNK-A/NK图解（Rickwood，1989；Le Maitre et al., 1989）；c-FAM图解（Irvine, 1971；TH—拉斑玄武岩系列；T—钙碱性火成岩系列）；d—SiO2-K2O图解（据Rickwood，1989；Le Maitre et al., 1989）
Figure 6. Diagrams of the volcanic rocks in the study area
a-TAS plot for the volcanic rocks(after Le Maitre, 1989; Pc-Picrite basalt; B-Basalt; O1-Basaltic andesite; O2-Andesite; O3-Dacite; R-Rhyolite; S1-Trachybasalt; S2- Basaltic trachyandesite; S3-Trachyandesite; T-Trachyte, trachydacite; F-Feldspathoidite; U1-Tephrite, basanite; U2-Phonolitic tephrite; U3-Tephriphonolite; Ph-Pphonolite; Ir-Irvine boundary, upper is basic, lowerw is alkaline); b-A/CNK-A/NK plot (after Rickwood, 1989; Le Maitre et al., 1989); c-FAM plot (after Irvine, 1971; TH-Tholeiite series; T- Calc-alkaline series); d-SiO2-K2O plot (after Rickwood, 1989; Le Maitre et al., 1989)
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图 7 火山岩微量元素原始地幔标准化蛛网图（a）和球粒陨石标准化稀土配分图（b）（原始地幔和球粒陨石标准值均引自Sun and McDonough, 1989）
Figure 7. Primitive mantle-normalized trace element spidergram (a) and chondrite-normalized REE patterns (b) of volcanic rocks (after Sun and McDonough, 1989)
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图 8 火山岩构造环境判别图解
a—Yb-Th/Ta图解（Michael et al., 2000）；b—Ta/Yb-Th/Ta图解（Michael et al., 2000）；c—火山岩戈蒂尼—里特曼指数图解（A区—非造山带地区火山岩；B区—造山带地区火山岩（岛弧及活动大陆边缘）；C区—A区、B区派生的碱性、富碱岩；J—日本火山岩）；d—Rb/10-Hf-Ta*3三角图解（Wood，1980）；e—Rb-（Yb+Ta）图解；f—Rb-（Y+Yb）图解（VAG—火山岛弧；WPG—板内；syn—COLG-同碰撞；ORG—洋中脊）
Figure 8. Discrimination diagrams illustrating tectonic setting of the volcanic rocks
a-Yb-Th/Ta diagram (after Michael et al., 2000); b-Ta/Yb-Th/Ta diagram (after Michael et al., 2000); c-logσ-logτ diagram (A-Non-orogenic volcanic zone; B-Orogenic volcanic zone; C-Alkaline and alkaline-rich derived from A and B; J-Japanese volcanic rocks); e- Rb-(Yb+Ta) diagram; f- Rb-(Y+Yb)diagram (VAG-Volcanic arc; WPG-Within plate; syn-COLG-Syn-collisional; ORG-Mid-ocean ridge)
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图 9 火山岩年龄-Isr值图
M—幔源型；MC—壳幔混合源；C-1—下部壳源型；C-2—上部壳源型
Figure 9. Age-Isr of volcanic rocks
M-Mantle source; MC- Crust and mantle source; C-1-Lower crust; C-2-Upper crust
表 2 研究区火山碎屑岩和潜火山岩锆石U-Pb分析结果
Table 2 Zircon U-Pb dating results of the pyroclastic rock and subvolcanic rock in the study area
下载: 导出CSV
表 4 研究区火山岩微量元素测试结果（10-6）
Table 4 Trace elements (10-6) of volcanic rocks in the study area
下载: 导出CSV
表 5 研究区火山岩稀土元素测试结果（10-6）
Table 5 REE abundances (10-6) of volcanic rocks in the study area
下载: 导出CSV
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