Sphalerite Rb-Sr isotopic dating of the Dongyan Pb-Zn deposit in Southeastern Sichuan fold belt and its constraint on the timing of tectonic deformation
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摘要:
重庆西阳县洞岩铅锌矿床位于川东南褶皱带中，为一中低温热液铅锌矿床，预测Zn金属量10.14万t。矿（化）体主要沿NNE向、NWW向断层呈脉状分布，或沿层间破碎带呈似层状分布。赋矿围岩为奥陶系碳酸盐岩。川东南褶皱带中这一类型铅锌矿床的形成时代以及与NNE向断层相互关系研究薄弱。本文运用闪锌矿Rb-Sr同位素测年方法，测得洞岩铅锌矿床成矿年龄为（157.7±3.3）Ma，表明该矿床的主成矿阶段年龄为晚侏罗世。闪锌矿（87Sr/86Sr）i值为0.71347，远高于早期及同期沉积碳酸盐比值，可能与大气淡水加入有关。川东南褶皱带为推覆-滑脱的薄皮构造，褶皱变形的主要时期为中晚侏罗世的燕山运动早期。洞岩闪锌矿的Rb-Sr等线年龄与上述构造变形时代一致，说明矿床的形成与早燕山构造变形事件有关。
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关键词:
- 闪锌矿Rb-Sr定年 /
- 铅锌矿 /
- 燕山期 /
- 地质调查工程 /
- 川东南褶皱带
Abstract:The Dongyan Pb-Zn deposit located in the Southeast Sichuan folded belt is a middle-low temperature hydrothermal type lead and zinc deposit, predicted amount of Zn metal is 101400 tons. The orebodies occur along NNE- and NWW-trending faults in veined or stratoid form in the interlayer fracture zone and are hosted in Ordovician carbonate rocks. The formation of this type of Pb-Zn deposit in the southeastern Sichuan fold belt and the relationship with the NNE-trending fault remain unclear. In this paper, Rb-Sr isotopic dating yielded an age of (157.7±3.3) Ma for the sphalerite in the Dongyan Pb-Zn deposit, which represents the main metallogenic age of this deposit and also constrains the formation time of NNE-trending fault of this area. The (87Sr/86Sr)i ratio of the sphalerite is 0.71347, which is much more higher than the ratios of the same period or earlier period, and might have been related to atmospheric freshwater. The Southeast Sichuan folded belt of Sichuan Basin is a nappe-detachment thin skinned structure. The main period of the fold deformation was the early Yanshanian stage in the Middle-Late Jurassic period. Rb-Sr isochron age of Dongyan sphalerites is consistent with the tectonic deformation age mentioned above, indicating that the formation of the deposit was related to the Early tectonic deformation in Yanshanian stage.
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图 1 重庆酉阳、贵州沿河地区地质矿产简图
1—第四系；2—白垩系中统；3—二叠系—三叠系；4—志留系中下统；5—奥陶系；6—寒武系芙蓉统；7—寒武系第二、三统；8—实测断层及推测断层；9—整合地质界线及角度不整合地质界线；10—铅锌矿点；11—研究区
Figure 1. Geological sketch map of the study areas in Youyang, Chongqing and Yanhe, Guizhou Province
1-Quaternary; 2-Middle Cretaceous; 3-Permian-Triassic; 4- Middle-Lower Silurian; 5-Ordovician; 6-Cambrian Furongian Series; 7-Cambrian second and third series; 8-Measured fault and inferred fault; 9-Conformity geological boundary and angle unconformity geological boundary; 10- Lead-zinc deposit; 11-The study area
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图 2 洞岩铅锌矿床地质图
1—罗惹坪组；2—龙马溪组；3—湄潭组三段；4—湄潭组二段；5—湄潭组一段；6—红花园组；7—桐梓组三段；8—桐梓组二段；9—桐梓组一段；10—铅锌矿脉及编号；11—正断层；12—地层产状；13—地质界线；14—Zn异常；15—Cd异常；16—Ba异常；17—钻孔及编号；18—探槽及编号
Figure 2. Geological map of the Dongyan Pb-Zn deposit
1-Luoreping Formation; 2-Longmaxi Formation; 3-Third member of Meitan Formation; 4-Second member of Meitan Formation; 5-First member of Meitan Formation; 6-Honghuayuan Formation; 7- Third member of Tongzi Formation; 8-Second member of Tongzi Formation; 9-First member of Tongzi Formation; 10-Pb-Zn vein and its serial number; 11-Normal fault; 12-Bedding attitude; 13-Geological boundary; 14-Zn anomaly; 15- Cd anomaly; 16-Ba anomaly; 17-Drill holes and serial number; 18-Trench and serial number
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图 3 洞岩铅锌矿8线勘探剖面图(据徐贵侯等，2013修改➎)
1—灰岩；2—白云质灰岩；3—生物碎屑灰岩；4—砂屑灰岩；5—白云岩；6—铅锌矿体；7—断层破碎带；8—产状；9—钻孔及其编号；10—探槽及其编号
Figure 3. Geological section along No. 8 exploration line of the Dongyan Pb-Zn deposit (modified from Xu Guihou et al., 2013 ➎)
1-Limestone; 2-Dolomitic limestone; 3-Bioclastic limestone; 4-Sandstone limestone; 5-Dolomites; 6-Lead-zinc orebody; 7- Fault fracture zone; 8-Attitude; 9- Drill hole and its serial number; 10- Groove and its serial number
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图 4 洞岩铅锌矿床矿石显微照片(a、b单偏光；c、d反射光）及矿石特征与交切关系（e，f，g，h）
Sp—闪锌矿；Gn—方铅矿；Py—黄铁矿；Qtz—石英；Cal—方解石；Br—角砾岩
Figure 4. Hand specimens and photomicrographs of the Dongyan Pb-Zn deposit (a, b-Plainlight; c, d-Reflection light; e-h-Ore characteristics and intersecting relationship)
Sp-Sphalerite; Gn-Galena; Py-Pyrite; Qtz-Quartz; Cal-Calcite; Br-Breccia
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图 5 洞岩铅锌矿床闪锌矿Rb-Sr同位素等时线
Figure 5. Rb-Sr isochron line of sphalerites from the Dongyan Pb-Zn deposit
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图 6 洞岩铅锌矿闪锌矿1/Rb-87Rb/86Sr和1/Sr-87Sr/86Sr关系图
Figure 6. Diagrams of 1/Rb versus 87Rb/86Sr and 1/Sr versus 87Sr/86Sr of sphalerites from the Dongyan Pb-Zn deposit
表 1 洞岩矿床闪锌矿Rb-Sr同位素分析结果
Table 1 Rb-Sr dating results of sphalerites from the Dongyan lead-zinc deposit
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