Discovery of the Late Carboniferous adakite in the Erenhot-Hegenshan suture zone and intra-oceanic subduction of the Paleo-Asian Ocean
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摘要:
内蒙古二连—贺根山缝合带额很傲包图英云闪长岩体，出露于西乌旗梅劳特乌拉SSZ型蛇绿岩带北侧。为了确定该岩体的岩石成因类型，探讨其构造环境及古亚洲洋俯冲消亡过程，对该岩体进行了岩石学、地球化学和LA-ICP-MS锆石U-Pb年代学研究。额很傲包图英云闪长岩高硅富铝，富钠贫钾，高锶低钇，富集Rb、Ba、Sr等大离子亲石元素和LREE，亏损Nb、Ta、Ti、P等高场强元素和HREE，无明显Eu异常。岩石学和岩石地球化学特征表明，该英云闪长岩体为高Si埃达克岩（HSA），形成于岛弧环境，具有洋内俯冲洋壳+俯冲深积物部分熔融并与上覆地幔楔橄榄岩反应成因特征。锆石LA-ICP-MS U-Pb测年表明，额很傲包图英云闪长岩体的侵位年龄为（305.6±1.5）Ma，形成时代为晚石炭世。结合二连—贺根山缝合带石炭纪蛇绿岩、石炭纪—二叠纪岛弧型岩浆岩的时空分布与演化特征，认为古亚洲洋二连—贺根山洋盆在石炭纪—早二叠世处于以洋内俯冲为特征的大洋俯冲消亡过程中。
Abstract:The Ehenaobaotu tonalite is outcropped in the northern part of the Meilaotewula SSZ-type ophiolite of the Erenhot-Hegenshan suture zone in Xi Ujimqin Banner of Inner Mongolia. Based on the study of petrology, geochemistry and zircon LA-ICP-MS U-Pb geochronology, the genetic type and tectonic setting of the tonalite were determined, and the final closure time and subduction process of the Erenhot-Hegenshan ocean basin of the Paleo-Asian Ocean were discussed. The tonalite is characterized by high SiO2, Al2O3, Na2O, Sr and low K2O, Y contents, enrichment of Rb, Ba, Sr large ion lithophile elements and LREE, and depletion of Nb, Ta, Ti, P high field strength elements and HREE. There is no pronounced Eu anomaly. The lithological and geochemical characteristics show that the Ehenaobaotu pluton is a high Si adakite (HSA) formed in island arc, and was derived from patial melting of the intra-oceanic subductingd oceanic crust and sediment and subsequently reaction with overlying mantle wedge peridotite. Its U-Pb LA-ICP-MS dating yields (305.6±1.5) Ma and suggests that the Ehenaobaotu pluton was formed during Late Carboniferous. Combined with the study of spatio-temporal evloution of the Carboniferous ophiolites and Carboniferous-Permian island arc magmatic rocks in the Erenhot-Hegenshan suture, it is assumed that the Erenhot-Hegenshan oceanic basin of the Paleo-Asian Ocean was in the process of oceanic subduction characterized by intra-oceanic subduction during the Carboniferous-Early Permian.
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1. 研究目的（Objective）
松科二井，获取了从基底—火石岭组—沙河子组—营城组—登娄库组下部连续完整的原位岩心。本文对松科二井沙河子组上部的孢粉化石进行研究，为研究白垩纪地球温室气候和环境变化，建立服务“百年大庆”目标和基础地质研究的“金柱子”提供基础资料。
2. 研究方法（Methods）
孢粉样品采自松科二井3395.46~3901.35 m，岩性为黑色、灰黑色泥岩、粉砂质泥岩，层位为沙河子组上部。孢粉分析鉴定在吉林大学古生物学与地层学研究中心完成，具体过程为：每个样品取过筛的干样50 g，进行盐酸→氢氟酸→氢氧化钾→盐酸→硝酸→氢氧化钾→盐酸等分析处理，用筛选法将样品中的孢粉化石集中在试管中，制2个固定片在生物显微镜下鉴定。
3. 研究结果（Results）
依据松科二井3395.46~3901.35 m井段的孢粉化石演化特征，划分出两个孢粉组合。
（1）Leiotriletes sp.- Cyathidites australis - Chasmatosporites sp.组合（简称LCC组合），分布在3832.94~3901.35m井段。蕨类孢子占绝对优势，裸子类花粉较低，未见被子类花粉。蕨类孢子含量最高的是Cyathidites australis，其次是Leiotriletes sp.和Cyclogranisporites sp.，有时代意义的还有Cicatricosisporites exilis、C. minutaestriatus、C. splendidus、C.australiensis、Klukisporites sp.、Maculatisporites sp.、Triporoletes singularis、Trilobosporites tribotrys、Aequitriradites sp.和Polycingulatisporites reduncus等；裸子类花粉含量最高的是Chasmatosporites sp.，其次是Psophosphaera sp.，有时代意义的类型有Parvisaccites sp.、Erlianpollis minisculus、Paleoconifersp.、Pseudowalchia sp.和Classopollis sp.等。
（2）Klukisporites triangulus- Aequitriradites sp.- Pristinuspollenites sp.组合（简称KAP组合），分布在3395.46~3613.62 m井段。裸子类花粉百分含量（53.03%~72.13%）较高，其次为蕨类孢子（27.87% ~46.97%），未见到被子类花粉。裸子类花粉中含量最高的是Alisporites parvus，其次是Piceaepollenites sp.，含量较高的类型还有Chasmatosporites sp.、Pinuspollenites divulgatus和P. sp.等，有时代意义的还有Parvisaccites otagoensis、Erlianpollis minisculus、E. mediocris、Jiaohepollis sp.和Classopollis classoides等。蕨类孢子含量最高的是Klukisporites sp.，其次是Leiotriletes sp.和Cyathidites australis，含量较高的类型还有Cyclogranisporites sp.等，有时代意义的有Cicatricosisporites exilis、C.apiteretus、C. australiensis、Klukisporites triangulus、K.variegatus、Pilosisporites scitulus、Impardecispora sp.、Levisporites wulinensis、Triporoletes singularis、Trilobosporites humilis、Aequitriradites sp.和Schizaeoisporites sp.等。
含有早白垩世特有或在早白垩世繁盛的分子：Cicatricosisporites、Klukisporites、Pilosisporites、Maculatisporites、Impardecispora、Levisporites、Triporoletes、Trilobosporites、Aequitriradites、Schizaeoisporites、Polycingulatisporites、Parvisaccites、Paleoconiferus、Erlianpollis、Foveotriletes.和Classopollis等（图 1）。
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图 1 松科二井沙河子组部分孢粉化石（1-Cicatricosisporites exilis，样品号：SK2-375；2. -Cicatricosisporites minutaestriatus，标品号：SK2-385；3-Cicatricosisporites splendidus，标品号：SK2-385；4-Cicatricosisporites australiensis，样品号(sample number)：SK2-375；5-Levisporites wulinensis，样品号(sample number)：SK2-205；6. Aequitriradites sp.，样品号(sample number)：SK2-389; 7-Trilobosporites tribotrys，样品号(sample number)：SK2-389；8- Classopollis classoides，标品号：SK2-97；9-Erlianpollis minisculus，样品号(number)：SK2-395; 10. Parvisaccites sp.，样品号：SK2-395；11. Pilosisporites scitulus，标品号：SK2-201；12-Triporoletes asper，标品号(specimen number)：SK2-219；13. Foveotriletes subtriangulularis，样品号：SK2-219；14-Klukisporites triangulus，样品号(sample number)：SK2-205；15-Impardecispora sp.，样品号：SK2-201; 16-Schizaeoisporites polaris，样品号：SK2-173；17-Polycingulatisporites reduncus，标品号：SK2-395；18-Maculatisporites sp.，样品号：SK2-391。19-Chasmatosporites sp.，样品号：SK2-389; 20-Paleoconiferae sp.，样品号(sample number)：SK2-391;线段比例尺为10 μm, the scale of the line segment is 10 μm）Figure 1. Spores and pollen from the Lower Cretaceous Shahezi Formation in Well SK2上述2个孢粉组合分布在，属沙河子组上部，LCC组合蕨类孢子百分含量占绝对优势，裸子类花粉较少，从组合特点来看，可以与高瑞琪等人建立的沙河子组上部Granulatisporites-Lophotriletes-Cicatricosisporites组合大致对比，但上部的KAP组合层位显然高于高瑞琪等人建立的孢粉组合。与高瑞琪等人建立的孢粉组合相比，当前孢粉组合出现的有时代意义的孢粉类型更多且时代更新。
4. 结论（Conclusions）
两个孢粉组合海金砂科孢子繁盛，类型多样化，没有发现早期被子植物花粉；虽在蕨类孢子与裸子类花粉的百分含量及属种构成上明显不同，但出现的有时代意义的化石类型基本相同，其时代均为早白垩世早期。
5. 致谢（Acknowledgement）
本文为国家自然科学基金项目（41790451)和中国地质调查局项目（DD20190097）共同资助。孢粉化石由张淑琴研究员鉴定。
致谢: 审稿专家和编辑对稿件提出了建设性的修改意见，在此表示衷心的感谢。 -
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图 1 额很傲包图英云闪长岩大地构造单元图(a)(修改自Miao et al., 2008), 区域地质图(b), 地质图(c), 野外照片(d)和显微照片(e)
Figure 1. Tectonic unit map (a)(modified from Miao et al., 2008), regional geological map (b), geological map(c), field photograph (d) and photomicrograph (e) of the Ehenaobaotu tonalite
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图 2 额很傲包图英云闪长岩（PS1-10）锆石阴极发光图像及其LA-ICP-MS U-Pb年龄
Figure 2. Cathodoluminescent images and LA-ICP-MS U-Pb ages of zircons from the Ehenaobaotu tonalite
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图 3 额很傲包图英云闪长岩（PS1-10）锆石LA-ICP-MS U-Pb年龄谐和图和直方图
Figure 3. U-Pb concordia diagram and histograms of zircons from the Ehenaobaotu tonalite
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图 4 额很傲包图英云闪长岩铝饱和指数(A/NK-A/CNK)图解（据Maniar and Piccoli, 1989
Figure 4. Shand's index of the Ehenaobaotu tonalite (after Maniar and Piccoli, 1989)
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图 5 额很傲包图英云闪长岩TAS分类图（据Middlemost, 1994）
Figure 5. Total alkalis vs. silica(TAS) classification diagram of the Ehenaobaotu tonalite (after Middlemost, 1994)
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图 6 额很傲包图英云闪长岩An-Ab-Or分类图解（据O'Connor, 1965）
Figure 6. An-Ab-Or classification diagram of the Ehenaobaotu tonalite (after O'Connor, 1965)
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图 7 额很傲包图英云闪长岩稀土元素球粒陨石标准化配分模式(球粒陨石标准化数值据Boynton, 1984; 高Si埃达克岩据Martin et al., 2005)
Figure 7. Chondrite-normalized REE distribution patterns of the Ehenaobaotu tonalite (normalizing values after Boynton, 1984; High-SiO2 adakite after Martin et al., 2005)
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图 8 额很傲包图英云闪长岩微量元素原始地幔标准化蛛网图(原始地幔标准化数值据Sun and McDonough, 1989; 高Si埃达克岩据Martin et al., 2005)
Figure 8. Primitive mantle-normalized trace element spider diagram of the Ehenaobaotu tonalite(normalizing values after Sun and McDonough, 1989; High-SiO2 adakite after Martin et al., 2005)
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图 9 额很傲包图英云闪长岩Y-Sr/Y构造判别图解(据Defant and Drummond, 1990; Martin, 1999; 高Si埃达克岩据Martin et al., 2005）
Figure 9. Y-Sr/Y tectonic discriminant diagram of the Ehenaobaotu tonalite (after Defant and Drummond, 1990; Martin, 1999; High-SiO2 adakite after Martin et al., 2005)
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图 10 额很傲包图英云闪长岩SiO2-MgO、(CaO+NaO2)-Sr、Y-Sr/Y和SiO2-Nb图解(据Martin et al., 2005)
Figure 10. SiO2-MgO, (CaO+NaO2)-Sr, Y-Sr/Y and SiO2-Nb diagrams of the Ehenaobaotu tonalite(after Martin et al., 2005)
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图 11 额很傲包图英云闪长岩(Y+Nb)-Rb（a）及(Yb+Ta)-Rb（b）构造判别图解（据Pearce, 1984；高Si埃达克岩据Martin et al., 2005）
Figure 11. (Y+Nb)-Rb (a) and (Yb+Ta)-Rb (b) tectonic discriminant diagrams of the Ehenaobaotu tonalite(after Pearce, 1984; High-SiO2 adakiteafter Martin et al., 2005)
syn-collision granites(syn-COLG), volcanic arc granites(VAG), within plate (WPG) and normal and anomalous ocean ridge (ORG) granites
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图 12 额很傲包图英云闪长岩和梅劳特乌拉洋内弧火成岩构造组合成因与演化模式图
Figure 12. Genetic and evolution model of the Ehenaobaotu tonalite and igneous petrotectonic assemblage of the Meilaotewula intra-oceanic arc
表 1 额很傲包图英云闪长岩（PS1-10）LA-ICP-MS锆石U-Pb测试结果
Table 1 LA-ICP-MS U-Pb dating of zircons from the Ehenaobaotu tonalite
下载: 导出CSV
表 2 额很傲包图英云闪长岩主量（%）、微量和稀土（10-6）元素分析结果
Table 2 Major element(%), trace element and REE analyses(10-6)of the Ehenaobaotu tonalite
下载: 导出CSV
表 3 额很傲包图英云闪长岩和高Si埃达克岩平均成分
Table 3 Average compositions of the Ehenaobaotu tonalite and high-SiO2 adakites
下载: 导出CSV
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