Zircon U-Pb dating of the Yuangezhuang pluton in Muping of Shandong Province and its constraints on mineralization of Cu-Mo deposits
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摘要:
牟平院格庄岩体位于胶东东部，为燕山晚期形成的与斑岩型-矽卡岩型铜钼多金属矿床有关的岩体之一。获得院格庄岩体崖西、后野、西上寨3个单元二长花岗岩LA-ICP-MS锆石U-Pb定年结果分别为（118.10±0.66）Ma、（118.52±0.78）Ma、（118.80±0.67）Ma，皆为早白垩世晚期。岩石地球化学研究表明：岩石属于高钾钙碱性、准铝质系列（K2O/Na2O值为1.00~1.29、A/CNK=0.98~1.02）。轻重稀土元素分馏明显（（La/Yb）N=26.91~35.75），δEu=0.84~0.93，具弱负铕异常。高场强元素Nb、Ti、P元素强烈亏损，大离子亲石元素Rb、K、U富集。地球化学特征显示院格庄岩体为I型花岗岩，为壳幔同溶型花岗岩。该岩体对其周缘铜钼矿空间分布和成矿时代有显著的制约作用，具有铜钼多金属矿的成矿专属性。
Abstract:The Yuangezhuang Pluton located in the east of Jiaodong area,is formed in the late Yanshanian and is one of the granites associated with Cu-Mo polymetallic deposits hosted inporphyry and skarn. LA-ICP-MS zircon U-Pb dating of Yaxi unite,Houye unite and Xishangzhai unite from the Yuangezhuang monzonitic granite yields (118.10±0.66) Ma,(118.52±0.78) Ma,and (118.80±0.67) Ma respectively,indicating the Late Epoch of Early Cretaceous. The results of petrochemistry indicate the pluton is belong to high-K calc-alkaline serie (K2O/Na2O=1.00-1.29,A/CNK=0.98-1.02). The results of trace elements are characterized by dramatic fractionation between light REE and heavy (REE(La/Yb)N=26.91~35.75 unapparent Eu anomalies (δEu=0.84-0.93),enriched in LILE (i.e. Rb,K,U) and loss in HSFE (i.e. Nb,Ti,P). The geochemical characteristics indicate the Yuangezhuang pluton is an I type granite,crust-mantle syntectic granite. The pluton has strong constrain on spatial distribution and metallogenic epoch of Cu-Mo deposits.
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致谢: 审稿专家为论文提供了宝贵意见；天津地质调查中心田杰鹏博士和何江涛博士在试验测试工作方面给予了帮助，在此一并诚挚感谢！
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图 1 胶东主要金和铜钼矿床分布图（据李超等, 2016）
Figure 1. Regional geological map of Jiaodong area showing the distribution of main gold, copper and molybdenum deposits(after Li Chao et al., 2016)
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图 2 院格庄地区区域地质图（据山东省第三地质矿产勘查院, 1990）
Figure 2. Regional geological map of the Yuangezhuang area((afte No.3 Exploration Institute of Geology and Mineral Resources, Shandong Province, 1990)
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图 3 院格庄岩体野外地质特征
a—崖西单元钾长石斑晶密集分布；b—崖西单元闪长质包体；c—后野单元钾长石巨斑呈定向组构；d—后野单元钾长石巨斑；e—西上寨单元岩石野外地质特征；f—西上寨单元钾长石斑晶
Figure 3. Geological characteristics of Yuangezhuang pluton
a-K-feldspar phenocrysts are densely distributed Yaxi unite; b-Diorite inclusions in Yaxi unite granite; c-K-feldspar phenocrysts of Houye unite are in a directional arrangement; d-K-feldspar phenocrysts of Houye unite; e-The geological characteristics of Xishangzai unite granite in the field; f-K-feldspar phenocrysts in Xishangzai unite
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图 4 崖西单元样品2017N1锆石阴极发光图像
Figure 4. Representative CL images and U-Pb ages of zircons from samples 2017N1 collected from Yaxi unite
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图 5 崖西单元样品2017N1 LA-ICP-MS锆石U-Pb年龄谐和年龄图
Figure 5. LA-ICP-MS zircon U-Pb concordia diagram of samples 2017N1 form Yaxi pluton
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图 6 后野单元样品2017N2锆石阴极发光图像
Figure 6. Representative CL images and U-Pb ages of zirons from samples 2017N2 collected from Houye unite
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图 7 后野单元样品2017N2 LA-ICP-MS锆石U-Pb谐和年龄图
Figure 7. LA-ICP-MS zircon U-PbConcordia diagram of samples 2017N2 form Houye unite
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图 8 西上寨单元花岗岩样品2017N3锆石阴极发光图像及U-Pb年龄
Figure 8. Representative CL images and U-Pb ages of zirons from samples 2017N3 collected from Xishangzhai unite
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图 9 西上寨单元花岗岩样品2017N3 LA-ICP-MS锆石U-Pb谐和年龄图
Figure 9. LA-ICP-MS zircon U-Pb Concordia diagram of samples 2017N3 from Xishangzai unite
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图 10 岩石地球化学分类图
a—花岗岩TAS分类图（Middlemost, 1994）; b—碱性与亚碱性系列判别图（Irvine and Baragar, 1971）; c—岩石系列SiO2-K2O图解（Peccerillo and Taylor, 1976）; d—岩石类型A/CNK-A/NK图解（Maniar and Piccoli, 1989）
Figure 10. Geochemical classification diagrams of granite
a-TSA classification diagram of granite(Middlemost, 1994);b-Alkaline and alkaline diagiam for granite(Irvine and Baragar, 1971);c-K2O vs. SiO2 diagram for granite (Peccerillo and Taylor, 1976);d-A/NK vs. A/CNK diagram for granite (Maniar and Piccoli, 1989)
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图 11 院格庄岩体球粒陨石标准化稀土元素分布型式图(a, 球粒陨石标准化值据Boynton, 1984)及原始地幔标准化微量元素蛛网图(b, 原始地幔标准化值据Sun et al., 1989)
Figure 11. Chondrite-normalized REE patterns(a, chondrite normalized values after Boynton, 1984) and primitive mantle-normalized traceelement spidergrams (b, primitive mantle normalized values after Sun et al., 1989) for the Yuangezhuang pluton
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图 12 Ⅰ型花岗岩成因类型判别
a—(Zr+Nb+Ce+Y)-FeO/MgO图解; b—(Zr+Nb+Ce+Y)-(K2O+Na2O)/CaO图解; c—10000Ca/Al-FeO/MgO图解; d—10000Ca/Al-(K2O+Na2O)图解; e—10000Ca/Al-Nb图解; f—10000Ca/Al-Zr图解（据Whalen et al., 1987）
Figure 12. Diagram showing the genetic type of the I-type granite
a-Diagram of (Zr+Nb+Ce+Y) versus FeO/MgO; b-Diagram of (Zr+Nb+Ce+Y) versus (K2O+Na2O)/CaO; c-Diagram of 10000Ca/Al versus FeO/MgO; d-Diagram of 10000Ca/Al versus (K2O+Na2O); e-Diagram of 10000Ca/Al versus Nb; f-Diagram of 10000Ca/Al versus Zr(after Whalen et al., 1987)
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图 14 (Y+Nb)-Rb及Y-Nb构造环境判别图解（据Pearce et al., 1984）
Figure 14. The diagrams of (Y+Nb) vs. Pb and Y vs. Nb(after Pearce et al., 1984)
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图 15 牟平孔辛头铜钼矿床18线地质剖面图
（据山东省冶金地质勘探公司第三勘探队, 1979修改）
Figure 15. Sketch geological section along No.18 exploration line in the Kong Xintou Cu-Mo deposit, Muping
(modified from No.3 Geological Party of Metallurgical Geology Exploration Company Shandong Province, 1979)
表 1 院格庄岩体样品的LA-ICP-MS锆石U-Pb同位素分析结果
Table 1 LA-ICP-MS zircon U-Pb isotope analytical results of Yuangezhuang pluton
下载: 导出CSV
表 2 院格庄岩体的主量元素(%)、微量元素和稀土元素(10-6)化学成分
Table 2 Chemical compositions of major elements (%), trace elements and REE elements (10-6) of the Yuangezhuang pluton
下载: 导出CSV
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