Molybdenite Re-Os dating of the Qiucheng Mo deposit in Dehua of central Fujian Province and constraints on the mineralization time
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摘要:
福建德化邱埕钼矿床是德化-尤溪-永泰矿集区唯一一处规模较大的钼矿床。辉钼矿体分布在花岗斑岩外接触带，辉钼矿多沿中新元古代变质岩和晚侏罗世花岗岩裂隙分布，多呈浸染状、脉状和团块状。本次测得该矿床6件辉钼矿样品Re-Os模式年龄为150.1~152.8 Ma，187Re-187Os等时线年龄为（150.8±1.6）Ma，加权平均年龄为（151.8±0.9）Ma，表明成矿时代为晚侏罗世晚期，与该地区大规模的火山-侵入体活动相关；Re/Os比值远大于4，Re同位素含量14.31×10-6~45.8×10-6（最高达174.7×10-6），指示成矿物质主要来源于壳源，可能还有少量幔源物质的加入。邱埕钼矿床的形成可能为古太平洋板块朝东亚陆缘碰撞挤压作用结束向伸展作用转化过程的产物。
Abstract:The Qiucheng Mo deposit is located in the Dehua-Yongxi-Yongtai ore-concentrated area of Fujian Province. It is the only one large-scale molybdenum deposit there. Ore bodies are mainly distributed in the outer contact of granite porphyry, fissure filling of the middle-late Proterozoic metamorphic rocks and the late Jurassic granites. The molybdenite is disseminated, veins and lump. Re-Os dating of six molybdenite samples collected from the main ore body in the deposit yields the model age from 150.1 Ma to 152.8 Ma, the isochron age of(150.8±1.6)Ma, and the weighted average age of(151.8±0.9)Ma. It can thus be considered that the deposit was formed in the late stage of Late Jurassic and related to the large-scale volcanic and intrusive rock activities. According to the rhenium content(14.31×10-6-45.8×10-6(one is 174.7×10-6))and the ratio of Re and Os(much greater than 4)of molybdenum samples, it is inferred that the ore-forming materials of the deposit were mainly derived from the crust and possible addition of small amount of mantle materials. The Qiucheng Mo deposit may be the product of conversion process from the end of collision to the beginning of extension of the Paleo-Pacific plate towards the continental margin of East Asia.
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图 1 德化地区地质简图(据资料❶❷修改)
1—第四系; 2—早白垩世火山岩; 3—晚侏罗世火山岩; 4—晚侏罗世碎屑岩；5—中侏罗世碎屑岩；6—早侏罗世碎屑岩；7—三叠纪碎屑岩；8—二叠纪碎屑岩夹碳酸岩；9—中新元古代变质岩；10—早白垩世花岗斑岩；11—早白垩世钾长花岗岩；12—晚侏罗世花岗闪长岩；13—中侏罗世钾长花岗岩；14—中侏罗世二长花岗岩；15—三叠纪石英二长岩；16—志留纪石英闪长岩；17—志留纪闪长岩；18—地质界线和断层；19—火山口；20—金矿床或铜（铜金）矿床；21—钼矿；22—研究区
Figure 1. Regional geological map of the Dehua region (modified after research results report❶❷)
1-Quaternary; 2-Early Cretaceous volcanic rock; 3-Late Jurassic vocanic rock; 4-Late Jurassic clastic rock; 5-Middle Jurassic clastic rock; 6-Early Jurassic clastic rock; 7-Triassic clastic rock; 8-Permian clastic rock with carbonatite; 9-Middle and Late Proterozoic metamorphic rock; 10-Early Cretaceous granite porphyry; 11-Early Cretaceous moyite; 12-Late Jurassic granodiorite; 13-Middle Jurassic moyite; 14-Middle Jurassic monzonitic granite; 15-Triassic quartz monzonite; 16-Devonian quartz monzonite; 17-Devonian diorite; 18-Geologycal boundary and fault; 19-Volcanic vent; 20-Gold deposit or Copper(Copper-Gold)deposit; 21-Molybdenum deposit; 22-Research area
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图 2 福建德化邱埕矿区地质及采样位置图(据德化县邱埕矿业有限公司资料（2010）修改)
1—南园组第三段火山岩；2—南园组第二段火山岩；3—中新元古代变质岩；4—早白垩世花岗斑岩；5—晚侏罗世花岗岩；6—磁铁矿体；7—地质界线；8—断层；9—采样点位置
Figure 2. Geological map and sampling location of the Quiucheng deposit in Dehua, Fujian (modified from Qiucheng Mining Co., Ltd of Dehua County, 2010)
1-Volcanic rocks of the third member of the Nanyuan group; 2-Volcanic rocks of the third member of the Nanyuan group; 3-Middle and Late Proterozoic metamorphic rock; 4-Early Cretaceous granite porphyry; 5-Late Jurassic granite; 6-Magnetite ore; 7-Geological boundaries; 8-faults; 9-Sampling location
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图 3 福建德化邱埕—东措矿段岩石特征
a—灰白色花岗斑岩中见辉钼矿；b—红褐色花岗斑岩（γπK1）侵入变质岩（Pt2-3）
Figure 3. Lithologic characteristics of Qiucheng-Dongcuo ore block in Dehua County of Fujian Province
a—Molybdenite in the grayish-white granite porphyry; b—Red-brown granite porphyry(γπK1)intrude into the metamorphic rocks(Pt2-3)
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图 4 青岗矿段20线地质剖面略图（据张集泉，2013修改）
1—晚侏罗世花岗斑岩；2—早白垩世花岗斑岩；3—辉绿岩；4—石英脉；5—断层破碎带；6—断层或地质界线；7—矿体
Figure 4. No.20 geological section of the Qinggang ore block
1-Late Jurassic granite porphyry; 2-Early Cretaceous granite porphyry; 3-Diabase; 4-Quartz vein; 5-Fracture zone; 6-Faults or geological boundary; 7-Ore body
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图 5 邱埕矿床辉钼矿野外及镜下
a—斜长变粒岩中脉状辉钼矿；b—矽卡岩裂隙中脉状辉钼矿；c—团块状辉钼矿；d—显微镜下辉钼矿
Figure 5. Field and microscope photos of ores in the Qiucheng deposit
a-Vein molybdenites in plagioclase-granulite; b-Vein molybdenites in the fractures of skarn; c-Massive molybdenites; d-Molybdenite under the microscope
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图 6 福建德化邱埕矿区辉钼矿Re-Os同位素等时线年龄图（a）和模式加权平均年龄图（b）
Figure 6. Re-Os isochron age(a)and weighted average model ages(b)of molybdenite from the Qiucheng deposit in Dehua of Fujian
表 1 福建德化邱埕矿区辉钼矿Re-Os同位素模式年龄数据
Table 1 Re-Os model ages of molybdenite samples from the Qiucheng deposit in Dehua of Fujian
下载: 导出CSV
表 2 福建德化邱埕矿区Re-Os同位素测试空白水平
Table 2 Re-Os isotope age-dating blank background of the Qiucheng deposit in Dehua of Fujian
下载: 导出CSV
表 3 福建德化邱埕矿区及其附近矿床的成岩成矿年代统计
Table 3 Diagenetic and metallogenic ages of the Qiucheng deposit and adjacent deposits in Dehua of Fujian
下载: 导出CSV
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