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    冀中平原土壤阳离子交换量对冬小麦富集土壤重金属的影响

    The impact of soil cation exchange capacity on heavy metal accumulation in winter wheat of the North China Plain in Hebei Province

    • 摘要:
      研究目的 探讨土壤阳离子交换量与小麦籽粒富集土壤重金属的关系,为土壤污染风险管控与治理修复等工作提供科学依据。
      研究方法 基于冀中平原某表层土壤重金属含量偏高区域的土壤和小麦协同监测大数据,采用土壤阳离子交换量分级处理和多元统计分析等方法。
      研究结果 在0.05水平上建立土壤阳离子交换量与镉、砷、铜、铅、锌等重金属生物富集系数的回归模型:yCd=6.53+66.39×e−x/4.61、yAs=0.78−0.02x、yCu=6.78+40.51×e−x/6.15、yPb=0.21+1.79×e−x/3.62、yZn=19.44+65.64×e−x/6.36,调整后复相关系数分别为0.95、0.95、0.99、0.83、0.96,拟合优度均较好。
      结论 土壤有机质和机械组成中的黏粒组分是阳离子交换量的重要影响因素,且当其成为土壤阳离子交换量的主要影响因素时还会起到决定性作用;通过提升土壤阳离子交换量能有效降低小麦籽粒对土壤镉、铜、锌、铅、砷等重金属元素的富集,但当土壤阳离子交换量超过某一阈值时,随着土壤阳离子交换量的升高,小麦籽粒对土壤金属富集程度的下降趋势将逐步或明显放缓;研究区土壤阳离子交换量影响小麦籽粒富集土壤镉、铜、锌、铅等重金属元素的阈值分别为13.89 cmolc/kg、13.72 cmolc/kg、17.05 cmolc/kg、15.06 cmolc/kg。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective To provide a scientific foundation for soil pollution risk management and remediation, the relationship between soil cation exchange capacity and the buildup of heavy metals in wheat grains was investigated.
      Methods Regression models linking soil cation exchange capacity to the bioaccumulation coefficients of heavy metals such as cadmium, arsenic, copper, lead, and zinc were developed at the 0.05 level using soil cation exchange capacity classification treatment and multivariate statistical analysis techniques based on extensive collaborative monitoring data for soil and wheat in an area with high concentrations of heavy metals in the surface soil of Hebei Province's central plain.
      Results yCd=6.53+66.39×e−x/4.61, yAs=0.78−0.02x , yCu=6.78+40.51×e−x/6.15, yPb=0.21+1.79×e−x/3.62, yZn=19.44+65.64×e−x/6.36. The goodness of fit was good, and the corrected multiple correlation coefficients were 0.95, 0.95, 0.99, 0.83, and 0.96, respectively.
      Conclusions The findings showed that soil organic matter and the percentage of clay in the mechanical composition were significant determinants of soil cation exchange capacity and may be crucial when they take center stage. The accumulation of heavy metals, including cadmium, copper, zinc, lead, and arsenic, in wheat grains can be efficiently reduced by increasing soil cation exchange capacity. However, the decline in soil metal buildup in wheat grains gradually or dramatically slows as soil cation exchange capacity rises above a particular threshold. In the research region, cadmium, copper, zinc, and lead accumulation in wheat grains were affected by soil cation exchange capacity thresholds of 13.89 cmolc/kg, 13.72 cmolc/kg, 17.05 cmolc/kg and 15.06 cmolc/kg, respectively.

       

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