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    赣南典型钨矿及其周边土壤重金属风险评价及其来源解析

    Risk assessment and source apportionment of soil heavy metals in and around a typical tungsten mines, southern Jiangxi

    • 摘要:
      研究目的 金属矿山重金属污染是确保绿水青山所面临的一大挑战,开展有色金属矿区土壤重金属污染的源解析及其风险评价可为污染精准防控及生态风险管理提供科学依据。
      研究方法 选取赣南某废弃钨矿及其周边区域为研究对象,系统采集了19件表层土壤(底泥)样品、10件岩石样品,采用X射线荧光光谱法(XRF)、电感耦合等离子体质谱法(ICP-MS)、原子荧光光谱法(AFS)测定土壤和岩石中重金属Cr、Ni、Cu、Zn、Pb、Cd、W、As和Hg含量,运用内梅罗综合污染指数法和潜在生态危害指数法进行了污染程度及潜在生态风险评价,利用蒙特卡罗模拟对土壤重金属进行健康风险评估,采用绝对因子得分-多元线性回归法(APCS-MLR)模型解析污染源及其贡献率,从而确定优控因子。
      研究结果 (1)研究区表层土壤重金属含量超过江西省的土壤背景值,达到1.03~146倍,其中W的累积特征最为显著,并存在As、Cd、Cu为主的超标情况,超标点主要位于河道、下游耕地以及尾矿附近;(2)风险评估显示,研究区存在不可忽视的健康风险,As是非致癌和致癌风险的核心驱动因子,而Cd是潜在生态风险的首要贡献者;(3)APCS-MLR解析表明,研究区土壤重金属主要有矿业开发源、母岩风化源、生活排放源和不确定源,贡献率分别为42.5%、38.6%、5.2%和13.7%,其中矿业源对W、Cd、Cu和As的贡献率分别为72.7%、84.9%、86.9%和37.3%;(4)根据重金属、污染源和风险之间关系的分析,确定矿山开采源为优控源,Cd为优控因子。
      结论 尽管矿区经生态复绿后人群暴露频率降低,健康风险实际低于模型计算值,但残留尾矿和废石持续释放重金属,潜在生态风险仍不容忽视。本研究通过定量溯源与风险评估相结合,为决策者制定目标控制政策、降低管理成本提供了有效依据,凸显了以Cd为关键节点的精准防控策略在类似矿业区的推广价值。

       

      Abstract:
      This paper is the result of environmental geological survey engineering.
      Objective Heavy metal pollution from metal mines poses a major challenge to maintaining ecological sustainability. Source apportionment and risk assessment of soil heavy metal pollution in non-ferrous metal mining areas can provide a scientific basis for targeted pollution control and ecological risk management.
      Methods An abandoned tungsten mine and its surrounding area in southern Jiangxi Province were selected as the study area. A total of 19 surface soil (sediment) samples and 10 rock samples were systematically collected. The concentrations of Cr, Ni, Cu, Zn, Pb, Cd, W, As, and Hg in soils and rocks were determined by X-ray fluorescence spectrometry (XRF), inductively coupled plasma-mass spectrometry (ICP-MS), and atomic fluorescence spectrometry (AFS). Pollution levels and potential ecological risks were evaluated using the Nemerow comprehensive pollution index and the potential ecological risk index, respectively. Health risks from soil heavy metals were assessed via Monte Carlo simulation. Source apportionment and contribution rates were quantified using the absolute principal component score-multiple linear regression (APCS-MLR) model, and priority control factors were identified accordingly.
      Results (1) Heavy metal concentrations in surface soils exceeded the soil background values of Jiangxi Province by factors of 1.03–146, with W showing the most pronounced accumulation. As, Cd, and Cu were the main elements exceeding regulatory standards, with exceedance sites concentrated along river channels, downstream farmlands, and areas near tailings. (2) Risk assessment revealed non-negligible health risks in the study area. As was the core driver of both non-carcinogenic and carcinogenic risks, while Cd was the primary contributor to potential ecological risk. (3) APCS-MLR identified four sources—mining activities, parent rock weathering, domestic emissions, and an unidentified source—with contributions of 42.5%, 38.6%, 5.2%, and 13.7%, respectively. The mining source contributed 72.7% of W, 84.9% of Cd, 86.9% of Cu, and 37.3% of As. (4) Based on the relationships among heavy metals, pollution sources, and risks, mining activities were identified as the priority control source and Cd as the priority control factor.
      Conclusion Ecological revegetation has reduced exposure frequency, and the actual health risk is lower than modeled values. However, residual tailings and waste rocks continue to release heavy metals, and the potential ecological risk should not be overlooked. By integrating quantitative source apportionment with risk assessment, this study provides an effective basis for policymakers to design targeted control policies and reduce management costs, and highlights the value of Cd-centered precision control strategies in similar mining areas.

       

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